Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3

Abstract

The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated.The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated.The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated.