Механiзм iнгiбуючої дiї фулерену C60 при окисненнi бензилового спирту

Abstract

It is shown that fullerene C60 breaks the chains of oxidation of benzyl alcohols at interaction with alkyl and peroxyl radicals. According to kinetic researches, the rate constants k7 (ROO·+ + C60) = 2.84 · 102, k8 (R· + C60) = 1 · 107 l/(mol · s), and the stoichiometric coefficient of chains termination reactions of oxidation f ≈ 2 at 50 ◦С.