Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions

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dc.contributor.authorZatovsky, I.V.
dc.contributor.authorSlobodyanik, N.S.
dc.contributor.authorUshchapivska, T.I.
dc.contributor.authorHan, W.
dc.date.accessioned2018-06-16T15:38:10Z
dc.date.available2018-06-16T15:38:10Z
dc.date.issued2017
dc.description.abstractThis article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %.uk_UA
dc.identifier.citationFormation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ.uk_UA
dc.identifier.issn1027-5495
dc.identifier.otherDOI: https://doi.org/10.15407/fm24.02.298
dc.identifier.urihttps://nasplib.isofts.kiev.ua/handle/123456789/136747
dc.language.isoenuk_UA
dc.publisherНТК «Інститут монокристалів» НАН Україниuk_UA
dc.relation.ispartofFunctional Materials
dc.statuspublished earlieruk_UA
dc.subjectTechnologyuk_UA
dc.titleFormation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditionsuk_UA
dc.typeArticleuk_UA

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Functional Materials, 2017, № 2