FTIR studies of annealing processes and irradiation effects at 266 nm in ozone-amorphous ice-mixtures

dc.contributor.authorChaabouni, H.
dc.contributor.authorSchriver-Mazzuoli, L.
dc.contributor.authorSchriver, A.
dc.date.accessioned2018-01-17T19:53:47Z
dc.date.available2018-01-17T19:53:47Z
dc.date.issued2000
dc.description.abstractFourier transform infrared (FTIR) spectroscopy is used to study the vibrational spectrum of ozone trapped in amorphous ice (a situation observed on icy satellites in the solar system). Evaporation of ozone from ice is investigated from 30 to 150 K under a static pressure of 10⁻⁷ Torr. Condensed and chemisorbed ozone on the surface of micropores is released at a temperature between 40 and 80 K, and ozone in water lattice evaporates starting from 120 K. The release of ozone probes the gradual transformation of water ice. The photochemistry of ozone in excess ice is also investigated using 266 nm laser irradiation. At low temperature, condensation of H₂O/O₃ mixtures leads to ozone trapped in pores and cavities, and H₂O₂ is produced through the hydrogen-bonded complex between ozone and free OH bonds. At higher temperature, when a solid solution of ozone in water is observed, H₂O₂ is formed by the reaction of the excited oxygen atom O(¹D) with the nearest water molecules. Kinetic studies suggest that recombination of the dioxygen molecule with ground-state atomic oxygen O(³P) is a minor channel.uk_UA
dc.identifier.citationFTIR studies of annealing processes and irradiation effects at 266 nm in ozone-amorphous ice-mixtures / H. Chaabouni, L. Schriver-Mazzuoli, A. Schriver // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 963-971. — Бібліогр.: 33 назв. — англ.uk_UA
dc.identifier.issn0132-6414
dc.identifier.otherPACS: 78.30.Hv, 71.55.Ht
dc.identifier.urihttps://nasplib.isofts.kiev.ua/handle/123456789/129218
dc.language.isoenuk_UA
dc.publisherФізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН Україниuk_UA
dc.relation.ispartofФизика низких температур
dc.statuspublished earlieruk_UA
dc.subjectLow-Temperature Physics and Chemistry in Cryomatriceuk_UA
dc.titleFTIR studies of annealing processes and irradiation effects at 266 nm in ozone-amorphous ice-mixturesuk_UA
dc.typeArticleuk_UA

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