Бiс(N-фенiлантранiлати) металiв в обривi ланцюгiв окиснення органiчних сполук

Abstract

It is shown that bis(N-phenylanthranilates) of metals ML2 (M = Mg, Ca, Sr, Ba) terminate the chains of oxidation of organic compounds by the reaction of peroxide radicals with co- ordinated > NH- and > N · -groups. At the oxidation of ethylbenzene (90 ◦ С), the rates of the reaction (C6H5CH(OO·)CH3+ML2) are measured: (3.8±0.2) · 104 (Ba), (2.8±0.3) · 104 (Ca), (1.2 ± 1) · 104 (Sr), (0.8 ± 0.1) · 104 l/(mol · s)(Mg).